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          UV光解治理石化行業(yè)VOCs— 打造“無(wú)異味工廠”

          來(lái)源:山西TT廢氣處理環(huán)保技術(shù)中心   2015年11月19日 09:46  

          山西TT高臭氧紫外線燈/整理
          Shanxi TT high ozone ultraviolet light / finishing

          UV光解治理石化行業(yè)VOCs— 打造“無(wú)異味工廠”
          UV efficient photolysis of governance in the petrochemical industry VOCs - to create a "no odor factory"

          天津石化始終將綠色環(huán)保與企業(yè)發(fā)展同步,連續(xù)十四年獲得全國(guó)“安康杯”競(jìng)賽優(yōu)勝企業(yè)稱號(hào)。近兩年,該公司又瞄準(zhǔn)打造“無(wú)異味工廠”的更高目標(biāo)展開攻堅(jiān)。
          Tianjin Petrochemical has always been green and enterprise development synchronization, for Fourteen consecutive years to obtain the national Ankang Cup winner of the competition. In recent two years, the company has aimed at building a "no smell factory" to start a more targeted.

          企業(yè)既然達(dá)標(biāo)排放,那么“異味”又是從何而來(lái)呢?天津石化安環(huán)部副部長(zhǎng)劉忠河介紹說(shuō),主要來(lái)自裝置中產(chǎn)生的揮發(fā)性有機(jī)物(VOCs),還有一部分無(wú)機(jī)硫化物。
          Enterprises since the emission standards, then the smell is coming from? Liu Zhonghe, deputy director of the Tianjin petrochemical, said the main come from the device to produce volatile organic compounds (VOCs), as there is a part of inorganic sulfide.

          異味治理是石油化工企業(yè)普遍存在的難題。對(duì)此,天津石化從生產(chǎn)管理、新技術(shù)應(yīng)用、源頭控制三方面用力,使揮發(fā)性有機(jī)物有組織排放和無(wú)組織排放均得到有效治理,并取得階段性成果。
          Odor control is a common problem in petrochemical enterprises. In this regard, Tianjin Petrochemical from production management, new technology application, the source control three aspects of the force, so that the volatile organic compounds have been effectively controlled by the organization and emissions of non organization, and achieved the stage results.

          只要環(huán)境保護(hù)需要的投資一分不少
          As long as the environmental protection needs of a lot of investment

          2016年1月1日,天津石化有一個(gè)橫亙?cè)诿媲靶枰畿S的新高度,那就是按照天津市實(shí)施的全國(guó)*《工業(yè)企業(yè)VOCs排放控制標(biāo)準(zhǔn)》,有組織排放源排放濃度必須執(zhí)行80mg/m3的zui高限值。這可是國(guó)內(nèi)、*水平。對(duì)此,天津石化主動(dòng)應(yīng)對(duì),嚴(yán)格對(duì)照新標(biāo)準(zhǔn)要求,全面排查識(shí)別有組織排放源,逐一研究制定治理措施。
          January 1, 2016, Tianjin Petrochemical have a lie in front of leap to a new height, that is according to Tianjin to implement the national first the industrial enterprises of VOCs emissions control standards ", emission source emission concentration must perform the 80mg, the maximum limit value. This is a domestic leader, the world's advanced level. In this regard, Tianjin Petrochemical active response, strict control of the new standard requirements, a comprehensive investigation and identification of the organization of emission sources, one by one to develop governance measures.

          “凡是有排放口的我們稱之為有組織排放,我們采用密閉改造、收集治理、增加治理設(shè)施等方式進(jìn)行了有效治理?!彼畡?wù)部安環(huán)科王全棟主任介紹。
          "We call that there is a discharge of emissions, we use the closed transformation, collection and management, and other ways to increase the management of facilities, such as effective governance." The water department director Wang introduced all the rings.

          三號(hào)污水處理場(chǎng)廢氣治理是天津石化“碧水藍(lán)天”工程重點(diǎn)項(xiàng)目之一,之前為敞開式處理,廢水中的酸性有機(jī)性氣體極易揮發(fā)。天津石化在對(duì)污水池進(jìn)行密閉改造后,新建了廢氣生物治理裝置,廢氣密封收集后輸送至廢氣生物處理裝置進(jìn)行處理,從根本上消滅了惡臭源。
          No. three sewage treatment field of waste gas treatment is Sinopec Tianjin "clear water and blue sky" project is one of the key projects, prior to the open type treatment, wastewater of organic acid gases are highly volatile. Tianjin petrochemical in the waste water tank after the transformation, the new waste gas biological treatment device, after the collection of waste gas seal to the waste gas biological treatment plant for processing, from the root of the source.

          截至目前,除已建成投用的十一套揮發(fā)性廢氣異味治理裝置外,煉油部、化工部、烯烴部等多個(gè)裝車棧臺(tái)密閉改造及油氣回收項(xiàng)目均在快馬加鞭建設(shè)中。
          Up to now, in addition to have been completed and voted with the set of 11 volatile gas odor control device, oil refining department, Ministry of chemical industry, olefin division multiple loading stacks Taiwan airtight transformation and oil gas recycling project in expediting the construction.

          近幾年來(lái),天津石化在異味治理,特別是在VOCs控制和治理上投資上億元?!坝挟愇叮f(shuō)明生產(chǎn)運(yùn)行中存在物料泄漏,而泄漏不僅是安全隱患、是效益的流失點(diǎn),更是企業(yè)健康可持續(xù)發(fā)展的瓶頸。因此,對(duì)于環(huán)保工作,天津石化一直堅(jiān)持‘三個(gè)一原則’,其中一條就是,只要環(huán)境保護(hù)需要的投資一分不少?!碧旖蚴箔h(huán)部劉忠河副部長(zhǎng)說(shuō)。
          In recent years, Tianjin petrochemical in the odor treatment, especially in the VOCs control and Governance on the investment of 100 million yuan. "There is a strange smell, the production operation of the existence of material leakage, and the leakage is not only a safe hidden trouble, is the loss of benefit, but also the sustainable development of enterprise health bottleneck. Therefore, the environmental protection work, Tianjin Petrochemical has always adhere to the 'three one principle, one of which is, as long as the need for environmental protection to invest a lot of investment." Tianjin petrochemical Liu Zhonghe, Deputy Minister of the Ministry said.

          新技術(shù)助力讓無(wú)組織排放受控
          New technology to help make no organization emissions control

          “以前有用肥皂水測(cè)試液化氣罐是否泄漏的做法。這種方法查出的泄漏至少在1.5萬(wàn)PPM以上,而我們采用LDAR泄漏檢測(cè)與修復(fù)技術(shù),超過(guò)500PPM即為泄漏。其靈敏度和度不言而喻?!碧旖蚴O(shè)備部皮偉主任形象地進(jìn)行了對(duì)比。
          "The previous useful soap test of liquefied gas tank leaks practice. This method is found in the leakage of at least 15000 PPM or more, and we use LDAR leak detection and repair technology, more than 500PPM that is leaking. Its sensitivity and accuracy is self-evident." Tianjin Petrochemical Equipment Department Director Piwei image were compared.

          作為天津市LDAR技術(shù)普查試點(diǎn)單位,天津石化從2014年7月份開始與市環(huán)科院、市環(huán)評(píng)中心及青島安工院等單位合作,進(jìn)行LDAR普查試點(diǎn)、示范工作。
          Tianjin city as the first LDAR technology census pilot units, Tianjin Petrochemical began in July 2014, and the city center, the EIA center and Qingdao,, and other units of cooperation, a pilot survey, demonstration.

          “我們需要逐套對(duì)照裝置的設(shè)計(jì)圖,按照VOC泄漏檢測(cè)方法和標(biāo)準(zhǔn)確定測(cè)試范圍,現(xiàn)場(chǎng)識(shí)別、建檔,之后現(xiàn)場(chǎng)檢測(cè),發(fā)現(xiàn)泄漏掛牌標(biāo)識(shí),及時(shí)進(jìn)行維修,直至再測(cè)達(dá)標(biāo)才能完成這一輪的檢測(cè)和修復(fù)?!逼ソ榻B。
          "We need by sets of control device design, in accordance with the VOC leak detection methods and standards determine range test, field identification, documentation, on-site inspection found leakage identification listed, timely maintenance until test-retest standard to complete the detection and repair." Pi Wei introduction.

          截至目前,天津石化已完成包括1000萬(wàn)噸/年常減壓在內(nèi)的36套煉油、化工、乙烯裝置LDAR檢測(cè)工作,共建立VOC范圍內(nèi)密封點(diǎn)檔案347269點(diǎn),泄漏點(diǎn)率0.79%,修復(fù)率73.9%。
          Up to now, Tianjin Petrochemical has completed including 10 million tons / year atmospheric and vacuum distillation, 36 sets of oil refining, chemical industry, ethylene device LDAR detection work, to establish VOC seal archives 347269, leak rate of 0.79%, the repair rate of 73.9%.

          下一步他們將編制單套裝置的檢測(cè)報(bào)告,分析、統(tǒng)計(jì)各組件的泄漏信息,為明年大修期間泄漏點(diǎn)修復(fù)做好準(zhǔn)備,同時(shí)梳理LDAR工作管理流程,制定相關(guān)技術(shù)要求,構(gòu)建VOCs無(wú)組織排放監(jiān)控體系,使LDAR工作常態(tài)化,為實(shí)現(xiàn)“無(wú)異味工廠”總體目標(biāo)夯實(shí)基礎(chǔ)。
          Next they will prepare the report on the detection of a single set of devices, analysis, statistical components of information leakage and overhaul next year for a period of relief the leak repair ready, also combing LDAR work flow management formulated relevant technical requirements, construct the VOCs emission monitoring system, the LDAR normalization, "no smell factory" overall goal of laying a solid foundation for the realization of.

          全員“圍攻”異味從源頭控制
          Full "siege" odor from the source control

          煉油部1號(hào)延遲焦化裝置焦炭塔七米平臺(tái)上正在進(jìn)行除焦作業(yè),聯(lián)合四車間外操高志濤巡檢經(jīng)過(guò)此處,隨身佩戴的硫化氫報(bào)警儀悄然無(wú)聲。他特意聞了聞,沒(méi)有以前除焦時(shí)*的異味。
          Oil refining Department No. 1 delayed coker seven meters platform is of decoking task, four joint workshop exercises high Zhitao inspection through here, carry wear hydrogen sulfide alarm instrument quietly. He has a smell, not previously in addition to the peculiar smell of coke.

          車間主任葉雄飛介紹,1號(hào)焦化冷焦水系統(tǒng)異味隱患治理項(xiàng)目,雖然不是天津石化“碧水藍(lán)天”項(xiàng)目,但因?yàn)殛P(guān)系到的職工的身心健康,依然得到了公司上下的關(guān)注,實(shí)施半年多來(lái)效果良好職工滿意。
          Workshop director Xiong Fei ye on the No. 1 coking coke cooling water system of odor risk management of the project, although not Sinopec Tianjin "clear water and blue sky" project, but because workers in relation to the physical and mental health, still received the company's attention, half a year to implement ago effect good employee satisfaction.

          “異味治理利國(guó)利民,zui受益的還是我們的職工。這些年的環(huán)保投入和治理效果,職工有目共睹,參與熱情非常高,職工關(guān)于安全環(huán)保的優(yōu)化建議和改進(jìn)措施占合理化建議的一半還多?!比~雄飛說(shuō)。
          "The smell of governance for the benefit of the country, or our employees. These years of environmental protection investment and governance effect, the workers to see, the enthusiasm is very high, the workers on the safety and environmental protection optimization suggestions and improvement measures accounted for more than half of the rationalization proposal." Ye Xiongfei said.

          天津石化對(duì)異味排放從源頭控制,生產(chǎn)上有預(yù)案、治理上有投入,特別是在針對(duì)裝置開停工吹掃、增加管線改造等特殊時(shí)期,加強(qiáng)對(duì)職工的培訓(xùn)和演練,確保治理措施執(zhí)行到位。他們還按照天津市新VOC排放標(biāo)準(zhǔn)及時(shí)優(yōu)化在建項(xiàng)目技術(shù)方案,確保項(xiàng)目建成后達(dá)到新標(biāo)準(zhǔn)要求,以環(huán)評(píng)促進(jìn)建設(shè)項(xiàng)目“本質(zhì)環(huán)?!保嵘经h(huán)境保護(hù)管理水平。
          Tianjin Petrochemical on odor emissions from the source control, production plan, management, investment, especially in the specific period for the device to open and shut down, increase pipeline reconstruction and other special times, strengthen training and training of workers, to ensure that the implementation of governance measures in place. They also in accordance with the new VOC emission standards in Tianjin to optimize the project technical plan to ensure the completion of the project to meet the new standard requirements, in order to promote the construction project environmental protection, environmental protection management level.

          前不久,國(guó)家環(huán)保部進(jìn)行VOCs簡(jiǎn)化核算辦法的可行性驗(yàn)證調(diào)研,首站選定天津石化。原本五天的工作量計(jì)劃兩天即圓滿完成。調(diào)研組領(lǐng)導(dǎo)感謝天津石化的得力配合并評(píng)價(jià)說(shuō),天津石化設(shè)備設(shè)施齊全,檢測(cè)與修復(fù)符合國(guó)家標(biāo)準(zhǔn),操作方法規(guī)范,為核算辦法的驗(yàn)證提供了可靠的依據(jù),這是他們調(diào)研的直接原因。
          Not long ago, the Ministry of environmental protection of the feasibility of VOCs simplified calculation method to verify the research, the first station selected Tianjin petrochemical. Five days of the original work plan for the successful completion of the two days. Research group leaders thanks to the Tianjin Petrochemical's strength with the combined evaluation, Tianjin petrochemical equipment, testing and repair in line with national standards, operating methods, for the verification of accounting methods to provide a reliable basis, which is the direct reason for their high efficiency research.

          “zui嚴(yán)苛的地方環(huán)保標(biāo)準(zhǔn),既是壓力,更是動(dòng)力?!碧旖蚴笨傆頃詡ピ跒I海新區(qū)工作會(huì)上表示,達(dá)標(biāo)排放是企業(yè)必須恪守的“紅線”,但全力打造“無(wú)異味工廠”,追求綠色低碳可持續(xù)的目標(biāo)永無(wú)止境。
          "The most stringent local environmental standards, both pressure and more power." Yu Xiaowei, deputy general manager of Tianjin petrochemical industry in Binhai New Area, said the company must comply with the red line, but to create a "no smell factory", the pursuit of green low-carbon sustainable goal.

          有機(jī)廢氣處理設(shè)備是山西TT廢氣處理環(huán)保技術(shù)中心推出的研發(fā)產(chǎn)品,它是UV光解除臭過(guò)濾組合裝置,利用特制的高能高臭氧UV紫外線光束照射惡臭氣體,裂解惡臭氣體如:氨、*胺、硫化氫、甲硫氫、甲硫醇、甲硫醚、二甲二硫、二硫化碳和苯乙烯,硫化物H2S、VOC類,苯、甲苯、二甲苯的分子鏈結(jié)構(gòu),使有機(jī)或無(wú)機(jī)高分子惡臭化合物分子鏈,在高能紫外線光束照射下,降解轉(zhuǎn)變成低分子化合物,如CO2、H2O等。
          Organic waste gas treatment equipment is Shanxi TT exhaust gas treatment Environmental Technology Center launched the latest Frierson special research and development products, it is -RSTUV light lift smelly filtration device, using special high-energy high ozone UV ultraviolet light irradiation malodorous gases, cracking malodorous gases such as ammonia and trimethylamine, hydrogen sulfide, dimethyl sulfide hydrogen, methanethiol, dimethyl sulfide, dimethyl disulfide, carbon disulfide and styrene, sulphide H2S and VOC classes, the molecular chain structure of benzene, toluene, xylene, organic or inorganic polymer odorous compounds molecular chain, in high-energy ultraviolet light irradiation, the degradation of transformation into low molecular weight compounds, such as CO2 and H2O.

          利用高能UV光束裂解惡臭氣體中細(xì)菌的分子鍵,破壞細(xì)菌的核酸(DNA),再通過(guò)臭氧進(jìn)行氧化反應(yīng),*達(dá)到脫臭及殺滅細(xì)菌的目的。
          The use of high energy UV beams to break the molecular bonds of the bacteria in the foul smelling gas, destroy the bacteria nucleic acid (DNA), and then through the ozone oxidation reaction, compley achieve the purpose of killing bacteria.

          山西TT廢氣處理環(huán)保技術(shù)中心的有機(jī)廢氣處理設(shè)備適用于煉油廠、橡膠廠、化工廠、制藥廠、污水處理廠、垃圾轉(zhuǎn)運(yùn)站等惡臭氣體的脫臭凈化處理。
          The organic waste gas treatment equipment of the Shanxi TT waste gas treatment technology center is suitable for the treatment of oil refinery, rubber plant, chemical plant, pharmaceutical factory, sewage treatment plant, garbage transfer station, etc..

          目前山西TT廢氣處理環(huán)保技術(shù)中心正與各大環(huán)保企業(yè)及科研單位進(jìn)行洽談合作,歡迎環(huán)境處理有志之士與我們合作。
          The Shanxi TT exhaust gas treatment environmental technology center is working with the environmental protection enterprises and scientific research units to discuss cooperation, welcomed the environmental treatment of people with lofty ideals to cooperate with us.

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